Fañanás Mastral Lab

Sustainable Catalysis & Asymmetric Synthesis

Publications

2024 - 2019 2018 - 2013 2013 - 2008 2008 - 2005

2024

  1. 73

    Enantioselective synthesis of chiral BCPs

    I. Sánchez-Sordo, S. Barbeira-Arán and M. Fañanás-Mastral

    Org. Chem. Front. 2024, 11, 916-928.

    This article is part of the themed collection: 2024 Organic Chemistry Frontiers Review-type Articles

2023

  1. 72

    Catalytic Alkyne Allylboration: A Quest for Selectivity

    A. Chaves-Pouso, E. Rivera-Chao, and M. Fañanás-Mastral

    ACS Catal. 2023, 13, 12656–12664.

    Among the Most Read Articles in ACS Catalysis, October 2023
  2. 71

    Desymmetrization of meso-dibromocycloalkenes by copper-catalyzed asymmetric borylative coupling with alkynes

    I. Sánchez-Sordo, A. Chaves-Pouso, J. Mateos-Gil, E. Rivera-Chao, M. Fañanás-Mastral

    Chem Catal. 2023, 3, 100730.

  3. 70

    C–C bond formation via photocatalytic direct functionalization of simple alkanes

    A. Velasco-Rubio, P. Martínez-Balart, A. M. Álvarez-Constantino, M. Fañanás-Mastral

    Chem. Commun. 2023, 59, 9424-9444.

    This article is part of the themed collection: Chemical Communications HOT Articles 2023
  4. 69

    Copper-Catalyzed Enantioselective Borylative Allyl–Allyl Coupling of Allenes and Allylic gem-Dichlorides

    M. Piñeiro-Suárez, A. M. Álvarez-Constantino, M. Fañanás-Mastral

    ACS Catal. 2023, 13, 5578–5583.

    Most Read Article in ACS Catalysis, April/May 2023
  5. 68

    Heterometallic palladium-iron Metal-Organic Framework as a highly active catalyst for cross-coupling reactions

    E. Miguel-Casañ, M. D. Darawsheh, V. Fariña-Torres, I. J. Vitórica-Yrezábal, E. Andres-Garcia, M. Fañanás- Mastral, G. Mínguez Espallargas

    Chem. Sci. 2023, 14, 179-185.

2022

  1. 67

    Bifunctional Skipped Dienes through Cu/Pd-Catalyzed Allylboration of Alkynes with B2pin2 and Vinyl Epoxides

    N. Vázquez-Galiñanes, I. Velo-Heleno, M. Fañanás-Mastral

    Org. Lett. 2022, 24, 8244-8248.

    Top 20 Most Read Articles in Organic Letters in November 2022
  2. 66

    Direct C–H Allylation of Unactivated Alkanes by Cooperative W/Cu Photocatalysis

    P. Martínez-Balart, B.L. Tóth, Á. Velasco-Rubio, M. Fañanás-Mastral

    Org. Lett. 2022, 24, 6874-6879.

    Top 3 Most Read Articles in Organic Letters, Sep/Oct 2022. Highlighted in Synfacts: Synfacts 2022, 18, 1322
  3. 65

    Catalytic Lewis Base Additive Enables Selective Copper-Catalyzed Borylative α-C–H Allylation of Alicyclic Amines

    B. Pérez-Saavedra, A. Velasco-Rubio, E. Rivera-Chao, J.A. Varela, C. Saá, M. Fañanás-Mastral

    J. Am. Chem. Soc. 2022, 144, 16206-16216.

    Highlighted in Synfacts: Synfacts 2022, 18, 1213
  4. 64

    Enantio- and Diastereoselective Copper-Catalyzed Allylboration of Alkynes with Allylic gem-Dichlorides

    A. Chaves-Pouso, A. M. Álvarez-Constantino, M. Fañanás-Mastral

    Angew. Chem. Int. Ed. 2022, 61, e202117696.

    Hot Article. Frontispiece: Angew. Chem. Int. Ed. 2022, 61, e202282361

2021

  1. 63

    Stereoselective Synthesis of Highly Substituted 1,3-Dienes via “à la carte” Multifunctionalization of Borylated Dendralenes

    E. Rivera-Chao, M. Fañanás-Mastral

    Angew. Chem. Int. Ed. 2021, 60, 16922-16927.

2020

  1. 62

    Copper-catalyzed Protoboration of Borylated Dendralenes: A Regio-and Stereoselective Access to Functionalized 1,3-Dienes

    A. Chaves-Pouso, E. Rivera-Chao, M. Fañanás-Mastral

    Chem. Commun. 2020, 56, 12230-12233.

  2. 61

    Copper-catalyzed O-alkenylation of phosphonates

    N. Vázquez-Galiñanes, M. Andón-Rodríguez, P. Gómez-Roibás, M. Fañanás-Mastral

    Beilstein J. Org. Chem. 2020, 16, 611-615.

    Part of the thematic issue "Copper-catalyzed reactions for organic synthesis"
  3. 60

    Transmetalation as Key Step in the Diastereo- and Enantioselective Synergistic Cu/Pd-Catalyzed Allylboration of Alkynes with Racemic Allylic Carbonates

    J. Mateos, N. Fuentes-Vara, L. Fra, E. Rivera-Chao, N. Vázquez-Galiñanes, A. Chaves-Pouso, M. Fañanás-Mastral

    Organometallics 2020, 39, 740-745.

2019

  1. 59

    Copper-Catalyzed Enantioselective Allylboration of Alkynes: Synthesis of Highly Versatile Multifunctional Building Blocks

    E. Rivera-Chao, M. Mitxelena, J.A. Varela, M. Fañanás-Mastral

    Angew. Chem. Int. Ed. 2019, 58, 18230-18234.

2018

  1. 58

    Stereoselective Synthesis of Borylated 1,3-Dienes by Synergistic Cu/Pd Catalysis

    N. Vázquez-Galiñanes, M. Fañanás-Mastral

    ChemCatChem 2018, 10, 4817-4820.

    Invited (Young Researchers Series) Cover Feature
  2. 57

    Synthesis of Stereodefined Borylated Dendralenes by Copper‐Catalyzed Allylboration of Alkynes

    E. Rivera-Chao, M. Fañanás-Mastral

    Angew. Chem. Int. Ed. 2018, 57, 9945-9949.

  3. 56

    Synergistic Bimetallic Catalysis for Carboboration of Unsaturated Hydrocarbons

    E. Rivera-Chao, L. Fra, M. Fañanás-Mastral

    Synthesis 2018, 50, 3825-3832.

    Invited Review

2017

  1. 55

    Copper(I)-Catalyzed Tandem Carboarylation/Cyclization of Alkynyl Phosphonates with Diaryliodonium Salts

    B. Pérez-Saavedra, N. Vázquez-Galiñanes, C. Saá, M. Fañanás-Mastral*

    ACS Catal. 2017, 7, 6104-6109.

  2. 54

    Synergistic Copper/Palladium Catalysis for the Regio- and Stereoselective Synthesis of Borylated Skipped Dienes

    J. Mateos, E. Rivera-Chao, M. Fañanás-Mastral*

    ACS Catal. 2017, 7, 5340-5344.

  3. 53

    Catalytic Asymmetric Synthesis of Butenolides and Butyrolactones

    B. Mao, M. Fañanás-Mastral,* B.L. Feringa

    Chem. Rev. 2017, 117, 10502-10566.

  4. 52

    Copper-Catalyzed Arylation with Diaryliodonium Salts

    M. Fañanás-Mastral*

    Synthesis 2017, 49, 1905-1930.

    Invited Review
  5. 51

    Cu-Catalyzed enantioselective allylic alkylation with organolithium reagents

    V. Hornillos, S. Guduguntla, M. Fañanás-Mastral, M. Pérez, P.H. Bos, A. Rudolph, S.R. Harutyunyan, B.L. Feringa

    Nat. Protoc. 2017, 12, 493-505.

  6. 50

    [2+1] Cycloaddition of Catalytic Ruthenium Vinyl Carbenes: A Stereoselective Controlled Access to (Z)- and (E)-Vinyl Epoxypyrrolidines

    D. Padín, F. Cambeiro, M. Fañanás-Mastral, J.A. Varela, C. Saá

    ACS Catal. 2017, 7, 992-996.

2016

  1. 49

    Iterative catalyst controlled diastereodivergent synthesis of polypropionates

    D. Roke, M. Fañanás-Mastral,* B.L. Feringa

    Org. Chem. Front. 2016, 3, 1383-1391.

    Cover
  2. 48

    Tandem Long Distance Chain-Walking/Cyclization via RuH2(CO)(PPh3)3/Brønsted Acid Catalysis: Entry to Aromatic Oxazaheterocycles

    R. Bernárdez, J. Suárez, M. Fañanás-Mastral, J.A. Varela, C. Saá

    Org. Lett. 2016, 18, 642-645.

  3. 47

    Chiral Diarylmethanes via Copper-Catalyzed Asymmetric Allylic Arylation with Organolithium Compounds

    S. Guduguntla, V. Hornillos, R. Tessier, M. Fañanás-Mastral, B.L. Feringa

    Org. Lett. 2016, 18, 252-255.

2015

  1. 46

    tBuLi-Mediated One-Pot Direct Highly Selective Cross-Coupling of Two Distinct Aryl Bromides

    C. Vila, S. Cembellín, V. Hornillos, M. Giannerini, M. Fañanás-Mastral, B.L. Feringa

    Chem. Eur. J. 2015, 21, 15520-15524.

  2. 45

    Regio- and Enantioselective Copper-Catalyzed Allylic Alkylation of Ortho-Substituted Cinnamyl Bromides with Grignard Reagents

    N.C. van der Molen, T.D. Tiemersma-Wegman, M. Fañanás-Mastral,* B.L. Feringa

    J. Org. Chem. 2015, 80, 4981-4984.

  3. 44

    Catalyst-controlled reverse selectivity in C-C bond formation: NHC-Cu-catalyzed α-selective allylic alkylation with organolithium reagents

    S.F. Pizzolato, M. Giannerini, P.H. Bos, M. Fañanás-Mastral,* B.L. Feringa

    Chem. Commun. 2015, 51, 8142-8145.

  4. 43

    Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers via Copper-Catalyzed Asymmetric Allylic Alkylation of (Z)-Allyl Bromides with Organolithium Reagents

    M. Fañanás-Mastral,* R. Vitale, M. Pérez, B.L. Feringa

    Chem. Eur. J. 2015, 21, 4209-4212.

    Hot Paper
  5. 42

    Direct catalytic cross-coupling of alkenyllithium compounds

    V. Hornillos, M. Giannerini,C. Vila, M. Fañanás-Mastral, B.L. Feringa

    Chem. Sci. 2015, 6, 1394-1398.

  6. 41

    On the Mechanism of Cu-Catalyzed Enantioselective Extended Conjugate Additions: A Structure-Based Approach

    T. den Hartog, Y. Huang, M. Fañanás-Mastral, A. Meuwese, A. Rudolph, M. Pérez, A.J. Minnaard, B.L. Feringa

    ACS Catal. 2015, 5, 560-574.

  7. 40

    Pd-Catalyzed Cross-Coupling of Aryllithium Reagents with 2-Alkoxy-Substituted Aryl Chlorides: Mild and Efficient Synthesis of 3,3'-Diaryl BINOLs

    L.M. Castelló, V. Hornillos, C. Vila, M. Giannerini, M. Fañanás-Mastral,* B.L. Feringa

    Org. Lett. 2015, 17, 62-65.

2014

  1. 39

    Palladium-Catalyzed Anti-Markovnikov Oxidation of Allylic Amides to Protected β-Amino Aldehydes

    J.J. Dong, E.C. Harvey, M. Fañanás-Mastral, W.R. Browne, B.L. Feringa

    J. Am. Chem. Soc. 2014, 136, 17302-17307.

  2. 38

    Copper-catalysed α-selective allylic alkylation of heteroaryllithium reagents

    C. Vila, V. Hornillos, M. Fañanás-Mastral, B.L. Feringa

    Org. Biomol. Chem. 2014, 12, 9321-9323.

  3. 37

    Palladium-Catalysed Direct Cross-Coupling of Organolithium Reagents with Aryl and Vinyl Triflates

    C. Vila, V. Hornillos,M. Giannerini, M. Fañanás-Mastral, B.L. Feringa

    Chem. Eur. J. 2014, 20, 13078-13083.

    VIP + Cover
  4. 36

    Asymmetric synthesis of N,O-heterocycles via enantioselective iridium-catalysed intramolecular allylic amidation

    D. Zhao, M. Fañanás-Mastral, M.-C. Chang, E. Otten, B.L. Feringa

    Chem. Sci. 2014, 5, 4216-4220.

  5. 35

    Copper-Catalyzed Synthesis of Mixed Alkyl-Aryl Phosphonates

    M. Fañanás-Mastral,* B.L. Feringa

    J. Am. Chem. Soc. 2014, 136, 9894-9897.

  6. 34

    Palladium-catalysed direct cross-coupling of secondary alkyllithium reagents

    C. Vila, M. Giannerini, V. Hornillos, M. Fañanás-Mastral,* B.L. Feringa

    Chem. Sci. 2014, 5, 1361-1367.

  7. 33

    Chiral amides via copper-catalysed enantioselective conjugate addition

    A.K. Schoonen, M.A. Fernández-Ibáñez, M. Fañanás-Mastral, J.F. Teichert, B.L. Feringa

    Org. Biomol. Chem. 2014, 12, 36-41.

    Cover

2013

  1. 32

    Hindered Aryllithium Reagents as Partners in Palladium-Catalyzed Cross-Coupling: Synthesis of Tri- and Tetra-ortho-Substituted Biaryls under Ambient Conditions

    M. Giannerini, V. Hornillos, C. Vila, M. Fañanás-Mastral,* B.L. Feringa

    Angew. Chem. Int. Ed. 2013, 52, 13329-13333.

  2. 31

    Catalytic Direct Cross-Coupling of Organolithium Compounds with Aryl Chlorides

    V. Hornillos, M. Giannerini,C. Vila, M. Fañanás-Mastral,* B.L. Feringa

    Org. Lett. 2013, 15, 5114-5117.

  3. 30

    Synthesis of Optically Active β- or γ-Alkyl-Substituted Alcohols through Copper-Catalyzed Asymmetric Allylic Alkylation with Organolithium Reagents

    s. Guduguntla, M. Fañanás-Mastral,* B.L. Feringa

    J. Org. Chem. 2013, 78, 8274-8280.

  4. 29

    Direct catalytic cross-coupling of organolithium compounds

    M. Giannerini, M. Fañanás-Mastral, B.L. Feringa

    Nat. Chem. 2013, 5, 667-672.

  5. 28

    Enantioselective synthesis of almorexant via iridium-catalysed intramolecular allylic amidation

    M. Fañanás-Mastral,* J.F. Teichert, J.A. Fernández-Salas, D. Heijnen, B.L. Feringa

    Org. Biomol. Chem. 2013, 11, 4521-4525.

  6. 27

    Catalytic asymmetric conjugate addition of Grignard reagents to chromones

    C. Vila, V. Hornillos, M. Fañanás-Mastral, B.L. Feringa

    Chem. Commun. 2013, 49, 5933-5935.

  7. 26

    A novel catalytic asymmetric route towards skipped dienes with a methyl-substituted central stereogenic carbon

    Y. Huang, M. Fañanás-Mastral, A.J. Minnaard, B.L. Feringa

    Chem. Commun. 2013, 49, 3309-3311.

  8. 25

    Palladium-Catalyzed Selective Anti-Markovnikov Oxidation of Allylic Esters

    J.J. Dong, M. Fañanás-Mastral, P.L. Alsters, W.R. Browne, B.L. Feringa

    Angew. Chem. Int. Ed. 2013, 52, 5561-5565.

  9. 24

    Cu-Catalyzed Asymmetric Allylic Alkylation of Phosphonates and Phosphine Oxides with Grignard Reagents

    V. Hornillos, M. Pérez, M. Fañanás-Mastral, B.L. Feringa

    Chem. Eur. J. 2013, 19, 5432-5441.

  10. 23

    Copper-Catalyzed Enantioselective Allyl-Allyl Cross-Coupling

    V. Hornillos, M. Pérez, M. Fañanás-Mastral, B.L. Feringa

    J. Am. Chem. Soc. 2013, 135, 2140-2143.

  11. 22

    Asymmetric Conjugate Addition of Grignard Reagents to Pyranones

    B. Mao, m. Fañanás-Mastral, B.L. Feringa

    Org. Lett. 2013, 15, 286-289.

  12. 21

    Diversity-Oriented Enantioselective Synthesis of Highly Functionalized Cyclic and Bicyclic Alcohols

    B. Mao, M. Fañanás-Mastral, M. Lutz, B.L. Feringa

    Chem. Eur. J. 2013, 19, 761-770.

2012

  1. 20

    Asymmetric Allylic Alkylation of Acyclic Allylic Ethers with Organolithium Reagents

    M. Pérez, M. Fañanás-Mastral, V. Hornillos, A. Rudolph, P.H. Bos, S.R. Harutyunyan, B.L. Feringa

    Chem. Eur. J. 2012, 18, 11880-11883.

  2. 19

    Copper-catalyzed asymmetric ring opening of oxabicyclic alkenes with organolithium reagents

    P.H. Bos, A. Rudolph, M. Pérez, M. Fañanás-Mastra, S.R. Harutyunyan, B.L. Feringa

    Chem. Commun. 2012, 48, 1748-1750.

  3. 18

    Enantioselective Synthesis of Tertiary and Quaternary Stereogenic Centers: Copper/Phosphoramidite-Catalyzed allylic Alkylation with Organolitium Reagents

    M. Fañanás-Mastral, M. Pérez, P.H. Bos, A. Rudolph, S.R. Harutyunyan, F.L. Feringa

    Angew. Chem. Int. Ed. 2012, 51, 1922-1925.

  4. 17

    Highly Enantioselective Synthesis of 3-Substituted γ-Butenolides by Palladium-Catalyzed Kinetic Resolution of Unsymmetrical Allyl Acetates

    B. Mao, Y. Ji, M. Fañanás-Mastral, G. Caroli, A. Meetsma, B.L. Feringa

    Angew. Chem. Int. Ed. 2012, 51, 3168-3173.

  5. 16

    Oxidation of Alkenes with H2O2 by an in-Situ Prepared Mn(II)/Pyridine-2-carboxylic Acid Catalyst and the Role of Ketones in Activating H2O2

    J.J. Dong, P. Saisaha, T.G. Meinds, P.L. Alsters, E.G. Ijpeij, R.P. van Summeren, B. Mao, M. Fañanás-Mastral, J.W. de Boer, R. Hage, B.L. Feringa, W.R. Browne

    ACS Catal. 2012, 2, 1087-1096.

  6. 15

    Synthetic Approaches to Highlyl Functional β-Carboline Building Blocks via Allylic Amidation

    J.F. Teichert, M. Fañanás-Mastral, B.L. Feringa

    Synthesis 2012, 44, 409-416.

  7. 14

    Z-Selective Copper-Catalyzed Asymmetric Allylic Alkylation with Grignard Reagents

    M. Giannerini, M. Fañanás-Mastral, B.L. Feringa

    J. Am. Chem. Soc. 2012, 134, 4108-4111.

2011

  1. 13

    Catalytic asymmetric carbon-carbon bond formation via allylic alkylations with organolithium compounds

    M. Pérez, M. Fañanás-Mastral, P.H. Bos, A. Rudolph, S.R. Harutyunyan, B.L. Feringa

    Nat. Chem. 2011, 3, 377-381.

  2. 12

    [1,5]-Hydride Transfer/Cyclizations of ortho-Amino Alkynyl Fischer Carbene Complexes: A Useful Tool for the Synthesis of Quinoline Derivatives

    J. Barluenga, M. Fañanás-Mastral, A. Fernández, F. Aznar

    Eur. J. Org. Chem. 2011, -, 1961-1967.

  3. 11

    Catalytic Enantioselective Synthesis of Naturally Occurring Butenolides via Hetero-Allylic Alkylation and Ring-Closing Metathesis

    B. Mao, K. Geurts, M. Fañanás-Mastral, A.W. van Zijl, S.P. Fletcher, A.J. Minnaard, B.L. Feringa

    Org. Lett. 2011, 13, 948-951.

  4. 10

    Iridium-Catalyzed Asymmetric Intramolecular Allylic Amidation: Enantioselective Synthesis of Chiral Tetrahydroisoquinolines and Saturated Nitrogen Heterocycles

    J.F. Teichert, M. Fañanás-Mastral, B.L. Feringa

    Angew. Chem. Int. Ed. 2011, 50, 688-691.

  5. 9

    Stereoselective synthesis of syn and anti 1,2-hydroxyalkyl moieties by Cu-catalyzed asymmetric allylic alkylation

    M. Fañanás-Mastral, B. ter Horst, A.J. Minnaard, B.L. Feringa

    Chem. Commun. 2011, 47, 5843-5845.

2010

  1. 8

    Copper-Catalyzed Regio- and Enantioselective Synthesis of Chiral Enol Acetates and β-Substituted Aldehydes

    M. Fañanás-Mastral, B.L. Feringa

    J. Am. Chem. Soc. 2010, 132, 13152-13153.

2009

  1. 7

    Carbene Transfer Reactions from Chromium(0) to Gold(I): Synthesis and Reactivity of New Fischer-Type Gold(I) Alkenyl Carbene Complexes

    M. Fañanás-Mastral, F. Aznar

    Organometallics 2009, 28, 666-668.

2008

  1. 6

    [1,5]-Hydride Transfer/Cyclizations on Alkynyl Fischer Carbene Complexes: Synthesis of 1,2-Dihydroquinolinyl Carbene Complexes and Cascade Reactions

    J. Barluenga, M. Fañanás-Mastral, F. Aznar, C. Valdés

    Angew. Chem. Int. Ed. 2008, 47, 6594-6597.

  2. 5

    C-H Insertion Processes on Stabilized Indolyl and ortho-Aminophenyl Fischer Carbene Complexes: Synthesis of Azepino[3,2,1-hi] indole, Benzazepine and Indole Derivatives

    J. Barluenga, M. Fañanás-Mastral, F. Aznar

    Chem. Eur. J. 2008, 14, 7508-7512.

  3. 4

    Cascade Reactions of Dialkynyl Fischer Carbene Complexes Involving Intramolecular Alkyne Insertion Oriented to the Synthesis of Functionalized Polycycles

    J. Barluenga, M. Fañanás-Mastral, F. Andina, F. Aznar, C. Valdés

    Organometallics 2008, 27, 3593-3600.

  4. 3

    Diastereoselective Synthesis of Three-, Five-, Six-, and Seven-Membered Rings from Fischer Carbene Complexes and 4-Unsubstituted 1-Amino-1,3-Dienes

    F. Aznar, M. Fañanás-Mastral, J. Alonso, F.J. Fañanás

    Chem. Eur. J. 2008, 14, 325-332.

2007

  1. 2

    Extended Dötz-Like Cyclization Reactions Towards the Synthesis of Eight-Membered Ring-Containing Polycycles: Scope and Theroretical Studies

    J. Barluenga, M. Fañanás-Mastral, M.A. Palomero, F. Aznar, C. Valdés

    Chem. Eur. J. 2007, 13, 7682-7700.

2005

  1. 1

    A New Synthesis of Allyl Sulfoxides via Nucleophilic Addition of Sulfinyl Carbanions to Group 6 Fischer Carbene Complexes

    J. Barluenga, M. Fañanás-Mastral, F. Aznar

    Org. Lett. 2005, 7, 1235-1237.