Fañanás Mastral Lab

Sustainable Catalysis & Asymmetric Synthesis

Introduction

We are a research group active in the fields of Catalysis and Synthetic Organic Chemistry at the Center for Research in Biological Chemistry and Materials (CIQUS) at the University of Santiago de Compostela.

Our research interests focus on the development of atom-efficient and sustainabled reactions and asymmetric transformations. Concepts such as bimetallic catalysis, enantioselective synthesis and alkane functionalization are currently being explored in our lab.

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Latest News

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  1. We welcome Mingming Huang as a new postdoctoral researcher in our team!!

  2. A long story comes to an excellent end. Our method to switch selectivity in the borylative allyl-allyl cross-coupling via synergistic Cu/Pd catalysis has been published in JACS. A great collaborative effort comprising experimental work Nuria Vázquez-Galiñanes, Balázs L. Tóth and Martín Piñeiro-Suárez, and DFT calculations by Giuseppe Sciortino and Feliu Maseras (ICIQ). Congratulations to all!

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  3. We have developed a methodology for the enantioselective allylboration of acetylene gas that serves as a versatile tool for the stereodivergent synthesis of natural products. The work has been accepted in Angewandte Chemie. Congrats to Andrés and Andrea!

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  4. We welcome Théo Decrombecque from the Institut National des Sciences Appliquées de Rouen (France). Théo will be in the group as visiting student until 31 August.

  5. We welcome Prof. Rajasekhara Reddy Sabbasani from the School of Advanced Sciences - Vellore Institute of Technology (Vellore, India) who will be in the group as visiting professor until 20 June.

  6. Our work on the Enantioselective Synthesis of α-Chiral Bicyclo[1.1.1]pentanes via Multicomponent Asymmetric Allylic Alkylation, has been published in Organic Letters. Congratulations to Sergio and Irene!

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  7. We welcome Jose Luis Nova as a new postdoctoral researcher in our team!!

  8. Former PhD student Eva Rivera Chao has been awarded with the Extraordinary Doctorate Award (Premio Extraordinario de Doutoramento). Congratulations Eva!!!

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  9. We welcome Prof. Marcus Mandolesi Sá from the Universidade Federal de Santa Catarina (Florianópolis, Brazil) who will be in the group as visiting professor from 1 March to 31 July.

  10. Our review on Enantioselective synthesis of chiral BCPs has been published. Congrats to Irene and Sergio!

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Recent publications

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  1. 78

    Chemodivergent alkylation of trifluoromethyl alkenes via photocatalytic coupling with alkanes

    P. Martínez-Balart, Á. Velasco-Rubio, S. Barbeira-Arán, H. Jiménez-Cristóbal and M. Fañanás-Mastral

    Green Chem. 2024, DOI:, 10.1039/d4gc04176c.

  2. 77

    Cross-Coupling of Gaseous Alkanes with (Hetero)Aryl Bromides via Dual Nickel/Photoredox Catalysis

    A. M. Nair, P. Martínez-Balart, S. Barbeira-Arán, M. Fañanás-Mastral

    Angew. Chem. Int. Ed. 2024, 63, e202416957.

  3. 76

    Switching Selectivity in Borylative Allyl–Allyl Cross-Coupling through Synergistic Catalysis

    N. Vázquez-Galiñanes, G. Sciortino, M. Piñeiro-Suárez, B.L. Tóth, F. Maseras, M. Fañanás-Mastral

    J. Am. Chem. Soc. 2024, 146, 21977–21988.

  4. 75

    Enantioselective Allylboration of Acetylene: A Versatile Tool for the Stereodivergent Synthesis of Natural Products

    A. M. Álvarez-Constantino, A. Chaves-Pouso, M. Fañanás-Mastral

    Angew. Chem. Int. Ed. 2024, 63, e202407813.

  5. 74

    Enantioselective Synthesis of α-Chiral Bicyclo[1.1.1]pentanes via Multicomponent Asymmetric Allylic Alkylation

    S. Barbeira-Arán, I. Sánchez-Sordo, and M. Fañanás-Mastral

    Org. Lett. 2024, 26, 3784–3789.

  6. 73

    Enantioselective synthesis of chiral BCPs

    I. Sánchez-Sordo, S. Barbeira-Arán and M. Fañanás-Mastral

    Org. Chem. Front. 2024, 11, 916-928.

  7. 72

    Catalytic Alkyne Allylboration: A Quest for Selectivity

    A. Chaves-Pouso, E. Rivera-Chao, and M. Fañanás-Mastral

    ACS Catal. 2023, 13, 12656–12664.

  8. 71

    Desymmetrization of meso-dibromocycloalkenes by copper-catalyzed asymmetric borylative coupling with alkynes

    I. Sánchez-Sordo, A. Chaves-Pouso, J. Mateos-Gil, E. Rivera-Chao, M. Fañanás-Mastral

    Chem Catal. 2023, 3, 100730.

  9. 70

    C–C bond formation via photocatalytic direct functionalization of simple alkanes

    A. Velasco-Rubio, P. Martínez-Balart, A. M. Álvarez-Constantino, M. Fañanás-Mastral

    Chem. Commun. 2023, 59, 9424-9444.

  10. 69

    Copper-Catalyzed Enantioselective Borylative Allyl–Allyl Coupling of Allenes and Allylic gem-Dichlorides

    M. Piñeiro-Suárez, A. M. Álvarez-Constantino, M. Fañanás-Mastral

    ACS Catal. 2023, 13, 5578–5583.

Gallery

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Enjoying group activity at Humor Amarillo Park, Vigo. July 2024.
Celebrating together after Christmas dinner 2023.
Christmas dinner. December 2023
Having fun into the water, Ulla river. July 2023.
Rafting route, Ulla river. July 2023.
Rafting route, Ulla river. July 2023.
Group photo, ready to start the rafting excursion on the Ulla river. July 2023.
March 2023
PhD Defense Nuria Vázquez Galiñanes. March 2023.
PhD Defense Nuria Vázquez Galiñanes. March 2023.